Mood Indigo

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The triplet state of indigo.

Indigo is one of the most emblematic molecules for the color blue, and is believed in many cultures to be charged with unique talismanic properties. The vivid color and high stability of this dye have led to an almost mythical status, from the “tecklet” of the Hebrews (believed to be a mixture with Tyrian Purple), through the blue of Napoleon Bonaparte(s army uniforms, to its current applicatio...

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cis-Conformation of indigo in the coordination complex (indigo-O,O)(Cp*CrIICl).

The interaction of decamethylchromocene (Cp*2Cr) with indigo in the presence of a Cl- source yields the coordination complex (indigo-O,O)(Cp*CrIICl) (1) in which one Cp* ligand at chromium is substituted by indigo. Indigo adopts an unusual cis-conformation in 1, allowing the coordination of both indigo carbonyl groups to one CrII center. Complex 1 contains CrII with an S = 1 spin state and indi...

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ژورنال

عنوان ژورنال: ICGA Journal

سال: 1995

ISSN: 2468-2438,1389-6911

DOI: 10.3233/icg-1995-18201